Wednesday 18 November 2015

Atoms, shells ,Sub-shells and Orbitals


Atoms:

Everything is made of small particles called atoms.

The smallest division of  every matter  is atom.

Atoms are made up of sub-atomic particles called protons, neutrons and electrons.
Protons and neutrons are in the nucleus which is situated in the centre of an atom.

Electrons are in different energy levels (shells) around the nucleus . Energy level (shell) are the electron clouds around the nucleus. There are gaps between the shells. 

Diagram:











Sub-atomic particles
Relative mass
Relative charge
Protons
1
+1
Neutrons
1
  0
Electrons
             1             
          1840
-1
  
Atomic number and Mass number:

Atomic no. :
Atomic no. of an element are the total no. of protons in a nucleus of an atom of that element. Each elements in the periodic table have unique atomic no.

Atomic no. = Total no. of protons


In a neutral atom,

Total no. of protons = Total no. of electrons

Mass no. :
Mass no. of  an element are the  total no. of protons and neutrons in the nucleus of an atom of that element.
Mass no. = Total no. of protons + Total no. of neutrons.

Notation: 


                              A
          X
                             Z 

where,

A= Atomic no.
Z = Mass no.
X= Symbol of  any Element


     

For example:
       

                            40
          Ca
                            20


Here,

Mass no. = 40

Atomic no. = 20

Since it is a neutral atom  of an element,

No. of protons =No. of  electrons = 20

No. Neutrons = Mass no. –atomic no.
                       =   40 -20
                       =    20



Shells (Different Energy levels):

The space outside the nucleus are called shells. Shells exist as different energy levels for electrons in an atoms. It is just a cloud of  electrons around the nucleus. There is a gap between the shells.



Shells can be divided further into sub-shells and orbitals.

Sub-shell:
Shells are made up of sub-shells.
There are four types of sub-shell.
They are :

s-subshells,
p-subshells,
d-subshells,
and
f-subshells.

Orbitals:

It is the region of space around the nucleus where there is a high probability of finding an electron or a pair of electrons .
An Orbital can hold up to a maximum no. of  2 electrons in opposite spin. 

There are also four kinds of orbitals:

s- orbitals,
p- orbitals,
d- orbitals,
and
f- orbitals.

s- orbitals have round spherical shapes.
p- orbitals have dumbbell like shapes. The p- orbitals are like a pair of balloon attached together.

We only need to study about  the shape of  “s” and “p” orbitals in AS Chemistry. We don’t have “d” and “f” orbitals in our syllabus. The shape of “d” and “f” orbitals are much more complicated.

Diagram:











“s” sub-shells consists of  one “s” orbital . It is like the outer skin of orange fruit. 

Diagram:










“p” sub-shell consists of  three  “p” orbitals: Px , Py , Pz . They are all perpendicular to each other i.e. the three dumbbells are set at 90° to each other in “p” subshell.

Diagram:


We don’t have “d” and “f” sub-shell in our syllabus. They are much more complicated.

Shell no.
Sub-shell
Number of sub-shells in each shell
Maximum number of electrons in the shell
1
1s
1st shell has 1 sub-shell.
2
2
2s 2p
2nd shell has 2 sub-shells.
8
3
3s 3p 3d
3rd shell has 3 sub-shells.
18
4
4s 4p 4d 4f
4th shell has 4 sub-shells.
32

Sub-shell
Number  of  orbital(s)
Maximum number of electrons in the sub-shell.
s
1
2
p
3
6
d
5
10
f
7
14

An Orbital can hold up to a maximum no. of  2 electrons in opposite spin. 







                                      

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