Saturday, 16 January 2016

Chemical Test For Bromine 2:

2) Displacement reactions : Bromine can also displace  iodide ions from  a metal iodide compounds.

     Bromine  liquid  is added to the solution of Iodide ions:


Notes
·         Aqueous iodine i.e formed here is insoluble in water but soluble in
KI Solution forming I3- Ions.
·         To Identify the spectator ions,  we                 
need to consider some facts:
1) State Symbols
2) Oxidation no. of components in       
     a redox reaction.


Br2 (l)  +    2KI  (aq)  →  2KBr (aq)  +     I2 (aq)              
                                                   
Ionically,
Br2 (l) +  I - (aq)      →   2Br- (aq) +    I2 (aq)







At the end of the reaction , if the product mixture is shaken with CCl4 / Hexane/ Cyclohexane /, Two coloured layers are observed. 


 Iodine is less soluble in water but more soluble in CCl4 or hexane or cyclohexane since iodine is non-polar .

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